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[Spraying Examples] Heat Resistance and Insulation Properties

Various considerations are necessary, such as the environment and atmosphere during use, as well as the type of material.

Thermal spraying is a surface modification technology that involves melting and spraying materials such as metals, ceramics, and cermets using various heat sources to form functional coatings on the substrate surface. It generally has thermal properties such as heat resistance and thermal insulation, which are often required simultaneously. To improve heat resistance, it is necessary for the thermal spray material to have a high melting point and to be stable in high-temperature environments. To enhance thermal insulation, the thermal spray coating is required to have a porous structure and low thermal conductivity. 【Features】 ○ Various considerations are needed, such as the environment and atmosphere during use, and the type of material. ○ It has thermal properties such as heat resistance and thermal insulation. ○ Improvement of heat resistance → The thermal spray material must have a high melting point and be stable in high-temperature environments. ○ Improvement of thermal insulation → The thermal spray coating is required to have a porous structure and low thermal conductivity. For more details, please contact us.

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Comparison of Thermal Spraying Methods and Particle Flight Velocities

Processing is possible at high particle flight speeds! You can obtain a dense coating with high adhesion.

This document is a comparison of "spraying methods and particle flight speed." In plasma spray engineering, spraying can be performed at high particle flight speeds, allowing for the creation of dense coatings with high adhesion strength. Additionally, it includes the "relationship between particle flight speed, porosity, and adhesion strength." Please feel free to download it and read it. [Contents] ■ Comparison of spraying methods and particle flight speed ■ Relationship between particle flight speed, porosity, and adhesion strength *For more details, please refer to the PDF document or feel free to contact us.

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Thermal Spray Processing Glossary【5】

Thermal Spray Processing Glossary

● Re-melting treatment (Fusing) Melting the sprayed coating of self-fusing alloy powder in a flame or electric furnace after spraying. ● Insulation coating A coating formed for insulation purposes. ● Abradable coating A sprayed coating that has a property of being easily abraded. ● Masking When performing spray processing, masking the material to prevent blasting from affecting it during the blasting treatment. ● Pores Spaces contained within the sprayed coating (there are open pores and closed pores). ● Porosity The ratio of pores within the sprayed coating. ● Spraying materials Materials used for spraying, which include various types such as metals, ceramics, and cermets, available in forms like powder, wire, and rods. ● Self-fusing alloy An alloy made by adding boron and silicon to nickel-based, nickel-chromium-based, or cobalt-based alloys. A coating without pinholes can be obtained through re-melting treatment after spraying. ● Pre-treatment The process of roughening the state of the base material or performing masking as necessary before spraying.

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Thermal spray material: Powder for HVOF thermal spraying【2】

HVOF thermal spray coatings have few oxides and pores, and possess dense and strong adhesion strength as well as excellent wear resistance.

Fe 17Cr 11Mo 3Ni 3Si 3Cu 4B - corrosion and wear resistance. Ni 5Al - wear resistance and oxidation resistance. Ni 17Cr 4Fe 4Si 3.5B 1C - dense and hard. Ni 21.5Cr 8.5Mo 3Fe 0.5Co - superalloy powder. Ni 19Cr 18Fe 3Mo 1Co 1Ti - superalloy powder. Ni 19Cr 18Fe 3Mo 5(Nb + Ta) 0.5 A1 1Ti 0.05C - has oxidation resistance and corrosion resistance. Ni 20Cr 10W 9Mo 4Cu 1C 1B 1Fe - has sliding wear resistance and corrosion resistance. Ni 23Fe 16Cr 1.5Si - has heat resistance and oxidation resistance.

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Thermal spray material: Powder for HVOF thermal spraying【3】

HVOF thermal spray coatings have few oxides and pores, and possess dense and strong adhesion strength as well as excellent wear resistance.

WC 12Co is excellent against abrasion and erosion. Ideal as an alternative to hard chrome plating. W₂C/WC 12Co has abrasion and erosion resistance. WC 10Co 4 Cr has abrasion and erosion resistance. WC 17Co has excellent toughness and fretting wear resistance. WC 12Co has excellent corrosion resistance. Resistant to abrasion and fretting. (WC 12Co) 33Ni 9Cr 3.5Fe 2Si 2B is very dense. WC 12Co 35(Cr₃C₂/20(Ni Ce)) has high corrosion resistance. Good abrasion, erosion, and fretting resistance.

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Thermal spray material: Carbide【1】

It is used to increase surface hardness and to provide wear resistance.

●Tungsten Carbide Based Tungsten Oxide Base Powders WC 12Co: Excellent abrasion resistance and erosion resistance. Has good sliding wear resistance. W₂C/WC 12Co: The coating is hard and dense, with good adhesion strength. Has good fretting wear resistance. WC 10Co 4Cr: Exhibits outstanding corrosion resistance, erosion resistance, and abrasion resistance. WC 17Co: Possesses excellent toughness and fretting wear resistance. WC 17Co: Has high toughness and fretting wear resistance. Provides protection against sliding wear, impact wear, abrasion, and fretting wear. WC 20Co: The coating is very rough, recommended for applications related to pulling and gripping. (WC 12Co) 25 (Ni Base Superalloy): Exhibits excellent corrosion resistance, abrasion resistance, and fretting resistance. 75 (WC 12Co) 17.5 Ni 4.3Cr 1.0Fe 1.0Si 1.0B 0.2C: Possesses outstanding erosion resistance and abrasion resistance. (WC 12Co) 35 (Cr₃C₂/20(Ni Cr): Has high corrosion resistance. Good abrasion resistance and erosion resistance.

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Thermal spray material: Carbides【2】

It is used to increase surface hardness and to impart wear resistance.

●Chromium Oxide Based Powders Cr₃C₂ Self-Fusing Nickel Alloy: Recommended for wear resistance, abrasion resistance against hard surfaces, fretting wear resistance, and particle erosion resistance. Cr₃C₂ 7(Ni 20Cr): Has the highest durability against fretting and wear at high temperatures. Cr₃C₂ 20(Ni 20Cr): Recommended for severe wear and fretting wear. Exhibits excellent particle erosion resistance. Cr₃C₂ 25(Ni 20Cr): Has good abrasion resistance, particle erosion resistance, cavitation resistance, and fretting wear resistance. Also has good corrosion resistance. Cr₃C₂ 50(Ni 20Cr): Recommended for wear and abrasion resistance against hard surfaces at rising temperatures between 540°C and 815°C. Cr 39Ni 7C: Compared to other HVOF chromium carbide thermal spray powders, it has a higher yield efficiency.

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Thermal spray materials: metals, alloys, cermets【1】

It is used for surface modification to impart corrosion resistance, oxidation resistance, and wear resistance, or to add electrical conductivity and electromagnetic shielding.

● Pure Metals A1 99%: Excellent corrosion resistance in coastal areas and industrial environments. It has good electrical and thermal conductivity. It can be used for electromagnetic shielding due to its non-magnetic properties. Cu 99%: Has good electrical and thermal conductivity. Cu 99%: Has good electrical and thermal conductivity. Mo 99.5% / Mo 99%: The coating is hard and also tough. It has excellent wear resistance and outstanding anti-seizing properties. It has resistance to fretting and electrical arc erosion. Ni 99.5%: Can be used for buildup in the repair of defective nickel alloy components.

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Thermal spray materials: metals, alloys, cermets【3】

It is used to impart corrosion resistance, oxidation resistance, and wear resistance for surface modification, or to add electrical conductivity and electromagnetic shielding.

●Copper Base Powders Cu 10Al/Cu 9.5Al 1Fe: At low temperatures, it has moderate oxidation resistance, wear resistance, and fretting resistance, along with good anti-seizing properties. It can be used for overlay repair of copper alloy components. Cu 11.5Al 1.5Fe/Cu 38Ni: The coating is very dense, with few pores and oxidation. Cu 36Ni 5In: The coating is dense. It has good galling resistance and fretting resistance. ●Iron Base Powders Fe 3Al 3Mo 3C 0.1B: High carbon steel composite powder. Fe 16Cr 2Ni 0.2C: Mostly used for restoring worn areas. It also has corrosion resistance. Fe 17Cr 12Ni 2.5Mo 1Si 0.1C/Fe 17Cr 12Ni 2.5Mo 1Si 0.1C: Recommended for cavitation and erosion areas at low temperatures. Fe 17Cr 11Mo 3Ni 3Si 3Cu 4B 0.4C: Corrosion and wear resistance. Fe 18Mo 3C 0.25Mn: Used as a hard bearing surface with a low friction coefficient.

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Thermal spray materials: metals, alloys, cermets【7】

It is used to impart corrosion resistance, oxidation resistance, and wear resistance for surface modification, or to add electrical conductivity and electromagnetic shielding.

● Nickel-based Powders Ni 31Cr 11Al 0.6Y is used for protective purposes in high-temperature environments with thermal corrosion and oxidation. Ni 20Cr 10W 9Mo 4Cu 1C 1B 1Fe has wear resistance and corrosion resistance. It excels in high-temperature hardness and has scuffing and galling resistance. Ni 23Fe 16Cr 1.5Si has heat and oxidation resistance. Ni 5Mo 5.5Al/Ni 5Mo 5.5Al has moderate hardness and is used as a hard bearing surface and wear-resistant coating. ● Cermet Powders Al₂O₃ 30(Ni 20Al) has very high hardness and is resistant to abrasion and impact.

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Thermal spray material: thermal spray wire【1】

Generally, it is used for dimension restoration, decoration, and corrosion prevention. It is also suitable for on-site construction.

● Arc Wires for Arc Spraying Al 99.0% / Al 99.0% - Has weather resistance, chemical corrosion resistance, and high-temperature corrosion resistance, as well as electrical conductivity and thermal conductivity. Al 6Si - Harder than pure Al coating, but somewhat inferior in corrosion resistance. Cu 99.8% - Usable for electrical applications. Zn 99.9% + - Iron, zinc. Cu 9Al 1Fe - Dense and wear-resistant, particularly used for precision machine parts. Fe 13Cr 0.5Si 0.5Ni 0.5Mn 0.35C - High chromium stainless steel wire material. Exhibits excellent wear resistance and reliable corrosion resistance. Fe 18Cr 8.5Mn 5Ni 1Si 0.15C - Austenitic low carbon stainless steel material. Fe 28Cr 5C 1Mn - High chromium stainless material. Fe 21Mo 4B₄C - A cost-effective wire alternative to molybdenum. Ni 5Al - Used for dimensional restoration of nickel and nickel alloy components. Ni 5Mo 5.5Al - Exhibits wear resistance and particle erosion resistance. Ni 18Cr 6Al - Has high-temperature oxidation resistance and high-temperature corrosion resistance.

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Thermal spray material: Abradable【2】

Ablatable thermal spray materials are used when zero-clearance control is required for components that operate at high temperatures and high rotational speeds.

●Cobalt Base Abradables Co 25Ni 16Cr 6.5Al 0.5Y 15 Polyester, 4BN High-temperature abradable thermal spray. Co 25Ni 16Cr 6.5Al 0.5Y 20 Polyester, 7 BN Used for gap control in compressor housings. ●Copper Base Abradables Aluminum Bronze Alloy 10 polyester / Aluminum Bronze Alloy 14 polyester / Aluminum Bronze Alloy 95 (Cu 9.5Al 1Fe) 5 polyester Abradable thermal spray material for use at temperatures up to 650°C.

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Thermal spray material: Ceramic【1】

It is widely used for acid resistance, wear resistance, anti-friction wear resistance, high-temperature corrosion resistance, as well as for providing insulation and electrical insulation properties.

● Aluminum Oxide Based Powders 99.5₊ Al₂O₃ Highest insulation properties. 98₊ Al₂O₃ Dense coating. Al₂O₃ 3TiO₂ Good durability against wear, sliding wear, friction, and oxidation. Al₂O₃ 13TiO₂ Coating and usage are the same as Al₂O₃ + 3% TiO₂. Al₂O₃ 40TiO₂ Has wear resistance and erosion resistance. ● Chromium Oxide Based Powders Cr₂O₃ Dense and corrosion-resistant. Cr₂O₃ 2TiO₂ Dense and corrosion-resistant. Cr₂O₃ 5SiO₂ 3TiO₂ Has high wear resistance and corrosion resistance. Al₂O₃ 13TiO₂ Coating and usage are the same as Al₂O₃ + 3% TiO₂. Al₂O₃ 40TiO₂ Has wear resistance and erosion resistance.

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Thermal spray material: Ceramic【2】

It is widely used for acid resistance, wear resistance, anti-friction wear resistance, high-temperature corrosion resistance, as well as for providing thermal insulation and electrical insulation properties.

● Titanium Oxide Based Powders TiO₂ 99% - Has moderate wear resistance. TiO₂ 45Cr₂O₃ - Exhibits excellent wear resistance, abrasion resistance, heat resistance, and corrosion resistance. ● Zirconium Oxide Based Powders ZrO₂ 5CaO 0.5Al₂O₃ 0.4SiO₂ - Mainly used for thermal barrier coatings. ZrO₂ 24MgO - Mainly used for thermal barrier coatings. ZrO₂ 25CeO₂ 2.5Y₂O₃ - Ideal for making thermal barriers. ZrO₂ 18TiO₂ 10Y₂O₃ - Has outstanding scuffing resistance. ZrO₂ 8Y₂O₃ - Exhibits excellent thermal shock resistance and insulation properties. ZrO₂ 20Y₂O₃ - Stable coating even at high temperatures.

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Thermal spray material: Powder for HVOF thermal spraying【1】

HVOF thermal spray coatings have few oxides and pores, and possess dense and strong adhesion strength as well as excellent wear resistance.

● Aluminum Oxide Based Powders Cu 99% - Good electrical and thermal conductivity Cu 9.5Al 1Fe - Good machinability Co 28Mo 8Cr 2Si - Optimal for areas with poor lubricity Co 28Mo 17Cr 3Si - Excellent wear resistance at high temperatures, good resistance to thermal corrosion, and moderate durability Cr₃C₂ 7(Ni 20Cr) - Best durability against fretting and wear at high temperatures Cr₃C₂ 7(Ni 20Cr) - High microhardness and fine coating surface Cr₃C₂ 25(Ni 20Cr) - Has oxidation resistance and erosion resistance Cr₃C₂ 50(Ni 20Cr) - Has erosion resistance and corrosion resistance at high temperatures Cr₃C₂ 50(Ni 20Cr) - Recommended for wear and abrasion resistance against hard surfaces at rising temperatures between 540°C and 815°C Cr₃C 39Ni 7C - Ideal alternative to hard chrome plating Fe 30Mo 2C - Ideal alternative to hard chrome plating Fe 17Cr 12Ni 2.5Mo 1Si 0.1C - High-quality grade powder of austenitic nickel/chromium stainless steel

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Thermal spray materials: metals, alloys, cermets【2】

It is used to impart corrosion resistance, oxidation resistance, and wear resistance for surface modification, or to add electrical conductivity and electromagnetic shielding.

● Aluminum-based Aluminum Base Powders Al 12Si: Used for buildup in the repair of aluminum and magnesium alloy components. Al 25Fe 7Cr 5Ni: Self-bonding, with a dense coating. ● Cobalt-based Cobalt Base Powders Co 25.5Cr 10.5Ni 7.5W 0.5C: Has durability against wear from high temperatures, hard surface wear, fretting wear, and particle erosion wear. Co 28Mo 8Cr 2Si: Effective in reducing the impact from environments such as reducing atmospheres like hydrochloric acid, formic acid, sulfuric acid, oxidizing atmospheres like ferric chloride and nitric acid, and non-oxidizing atmospheres like phosphoric acid, acetic acid, and saltwater. Ideal for areas with poor or no lubrication. Exhibits excellent sliding wear resistance, good high-temperature corrosion resistance, and moderate oxidation resistance. Proprietary MCrA1Y's: Used as a binder with heat corrosion resistance and oxidation resistance, applied in thermal barrier coating (TBC) sections.

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Thermal spray materials: metals, alloys, cermets【4】

It is used for surface modification to impart corrosion resistance, oxidation resistance, wear resistance, or to add electrical conductivity and electromagnetic shielding.

● Iron Base Powders Fe 30Mo 2C - Recommended for wear resistance, abrasion resistance from hard bearing surfaces, and fretting wear resistance. Fe 37Ni 6Al - Generates heat during thermal spraying, forms a strong metallurgical bond with the substrate, and has oxidation resistance. Fe 35Ni 5Al 5Mo - Recommended for the repair/restoration of parts such as piston crowns and cylinder heads. Fe 38Ni 10Al - Generates heat during thermal spraying, forms a strong metallurgical bond with the substrate, and has oxidation resistance. ● Molybdenum Base Powders Mo 3C - Tough, hard, and has excellent sliding wear characteristics. Mo 25(NiCrBSiFe) - Has high wear resistance, low friction coefficient, and good scuffing resistance.

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Thermal spray materials: metals, alloys, cermets【5】

It is used to impart corrosion resistance, oxidation resistance, and wear resistance for surface modification, or to add electrical conductivity and electromagnetic shielding.

● Nickel-based Powders Ni 4.5 Al/Ni 5Al: Dense, with oxidation resistance and abrasion resistance. Self-bonding material. The powder itself generates heat during thermal spraying, creating a metallurgical bond with the substrate. Ni 18Al/Ni 20Al: Dense, with excellent oxidation resistance and abrasion resistance. Ni 23Co 20Cr 8.5Al 4Ta 0.6Y: Coating with resistance to high-temperature corrosion and oxidation. Ni 9.5Cr 2.5Si 1.5B 0.5Al: Recommended for parts requiring wear resistance, particle erosion resistance, and cavitation resistance. Ni 20Cr: Intended for oxidation resistance and gas corrosion resistance. Ni 14Cr 2(Nb+Ta) 1 Ti 6Al 0.01B 0.1Zr 0.15C: Excellent oxidation resistance and corrosion resistance. Ni 17Cr 6Al 0.5Y: Used for protection in high-temperature environments with corrosive and oxidative atmospheres. Ni 16Cr 8Fe: Excellent machinability stainless steel coating. Ni 9Cr 5Al 5.5Mo 5Fe: Self-bonding, with outstanding oxidation resistance and corrosion resistance.

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Thermal spray materials: metals, alloys, cermets【6】

It is used to impart corrosion resistance, oxidation resistance, and wear resistance for surface modification, or to add electrical conductivity and electromagnetic shielding.

● Nickel-based Nickel Base Powders (NiCr) 6Al Recommended as an oxidation and corrosion-resistant coating at high temperatures. Recommended for repair/welding of worn or mismanufactured nickel-based components, or when machining or corrosion resistance is required. Ni 17.5Cr 5.5Al 2.5Co 0.5Y₂O₃ Has oxidation and corrosion resistance. Ni 8.5Cr 7Al 5Mo 2Si 2B 2Fe 3TiO₂ A hard "stainless type" coating. Excellent wear resistance and very good corrosion/oxidation resistance. Ni 25Cr 6Al 0.4Y / Ni 22Cr 10Al 1.0Y Used for protective purposes in high-temperature environments with thermal corrosion and oxidation. Ni 21.5Cr 8.5Mo 3Fe 0.5Co Most commonly used for surface restoration of worn or damaged parts. Equivalent to Inconel625. Ni 19Cr 18Fe 3Mo 1Co 1Ti Used for repairing worn areas or mismanufactured parts of Inconel718 components. Ni 19Cr 18Fe 3Mo 5(Nb+Ta) 0.5Al 1Ti 0.5C Excellent oxidation and corrosion resistance. Specifically designed for thermal spraying on Inconel713 and 718.

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Thermal spray material: thermal spray wire【2】

Generally, it is used for dimension restoration, decoration, and corrosion prevention. It is also suitable for on-site construction.

● Arc Wires for Thermal Spraying Designed for the restoration of parts made from Inconel 718, which consists of Ni 19Cr 18Fe 3Mo. Designed for the restoration of parts made from Inconel 625, which consists of Ni 21.5Cr 8.5Mo 3Fe 0.5Co. Sn 7.5Sb 3.5Cu 0.25Pb is dense. C 276 Ni Alloy is recommended for the repair/restoration of parts exposed to harsh corrosive environments. ● Combustion Wires for Metallizing Thermal Spraying Mo 99.9% - Molybdenum. Sn 99.9% - Tin wire material. Zn 99.9% + - Zinc. Cu 40Zn 0.8Sn 0.75Fe 0.24Mn - Tobin bronze. Fe 17Cr 12Ni 2.5Mo 2Mn 1Si 0.8C - SUS 316 type austenitic stainless steel.

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Thermal spray material: thermal spray wire【3】

Generally, it is used for dimension restoration, decoration, and corrosion prevention. It is also suitable for on-site construction.

●Combustion Wires for Metarizing Thermal Spraying Fe 4Ni 2Mn 1.5Mo 1.5Cr 0.04C 0.03P 0.03S is an easy-to-handle steel material. The Ni 20Al coating is dense and has oxidation resistance, and it can also withstand high temperatures and various temperature changes. Ni 20Al 20Fe 4Cr 4 is a hard stainless steel type coating. It has good wear resistance, corrosion resistance, and oxidation resistance. Ni 22.5Fe 16Cr 1.5Si is particularly optimal for areas requiring heat corrosion resistance.

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Thermal spray material: self-fusing alloy【1】

It forms a homogeneous coating that is metallurgically bonded to the substrate through fusion, without any through-holes.

● Nickel Base S/F Powders Ni 10Cr 2.5B 2.5Fe 2.5Si 0.15C shows durability against wear, hard surface wear, fretting wear, cavitation, and erosion. Ni 17Cr 4Fe 4Si 3.5B 1C has a very dense coating that is rich in corrosion resistance. Ni 16Cr 4Si 4B 3Cu 3Mo 2.5Fe 0.5C is used for added resistance to wear, hard surface wear, particle erosion, fretting wear, and cavitation. Ni 17Cr 4Fe 4Si 3.5B 1C / Ni 16Cr 4Si 4B 4Fe 2.4Cu 2.4Mo 2.4W 0.5C is a very dense self-fusing alloy coating. It has resistance to wear, hard surface wear, particle erosion, fretting wear, and cavitation. Ni 35 (WC 8Ni) 11Cr 2.5B 2.5Fe 2.5Si 0.5C is the most wear-resistant among self-fusing alloy materials.

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Thermal spray material: self-fusing alloy【2】

It forms a homogeneous film that is metallurgically bonded to the substrate through fusing, without any through-holes.

● Nickel-based Nickel Base S/F Powders Ni 35 (Wc 12Co) 11Cr 2.5Fe 2.5Si 2.5B 0.5C The coating has durability against erosion, wear, and fretting wear. (WC 12Co) 14Ni 3.5Cr 0.8B 0.8Fe 0.8Si 0.1C Exhibits excellent durability against wear, wear due to hard surfaces, fretting wear, and particle erosion. (WC 12Co) 33Ni 9Cr 3.5Fe 2Si 2B 0.5C Very dense. Has effective durability against wear, wear due to hard surfaces, particle erosion/abrasion, and fretting. ● Cobalt-based Cobalt Base S/F Powders Co 27Ni 18Cr 6Mo 3.5Si 3B 2.5Fe 0.2C Used for surface hardening of 400 series stainless steel and other low shrinkage base materials.

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Thermal spray material: Abradable【1】

Ablatable thermal spray materials are used when zero-clearance control is required for components that operate at high temperatures and high rotational speeds.

● Nickel Base S/F Powders Ni 15 Graphite / Ni 20 Graphite / Ni 25 Graphite - High-quality abradable thermal spray materials. They have self-lubricating properties and can be used in low-friction bearings. Ni 4Cr 4Al / Ni 4Cr 4Al 21 - High-quality abradable thermal spray materials. Ni 4Cr 8Fe 5.5BN 3.5Al - High-quality abradable thermal spray materials. ● Aluminum Base Abradables Al 8Si 20BN / Al 8Si 23 Graphite / Al 7Si 26 Graphite / Al 5.5Si 45.5 Graphite / Al 12Si Polyester / Al 12Si 40 Polyester / Al 12Si 47 Polyimide - High-quality abradable thermal sprays used in the compressor section of jet engines.

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